At , the reaction has . A mixture in a container at this temperature consists of 6 CO…

CHEMISTRY · Subjective · A Level · Chemistry · Chemical equilibria (Le Chatelier’s principle and Kc) · Chemical equilibria (Le Chatelier’s principle and Kc)

Problem

At 500 K500\,\text{K}, the reaction CO(g)+Cl2(g)  ⇌  COCl2(g)\text{CO}(g)+\text{Cl}_2(g)\;\rightleftharpoons\;\text{COCl}_2(g) has Kc=0.56K_c = 0.56. A mixture in a 1.0 L1.0\,\text{L} container at this temperature consists of 6 CO molecules, 6 Cl2_2 molecules, and 12 COCl2_2 molecules. The temperature is then increased so that KcK_c becomes 0.25, while the amounts of each species are momentarily unchanged. Based on a comparison of QcQ_c with the new KcK_c, predict whether the net reaction will shift toward the reactants or toward the products as equilibrium is re-established. Support your answer with appropriate reasoning.

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