Two single-electron species are considered: hydrogen ( ) and singly-ionised helium ( , ).

CHEMISTRY · Multi-part · CBSE · Chemistry · Structure of Atom · Structure of Atom

Problem

Two single-electron species are considered: hydrogen (Z=1Z=1) and singly-ionised helium (He+\text{He}^+, Z=2Z=2). (a) Derive an algebraic expression for the ratio vn (He+)vn (H)\dfrac{v_{n\,(\text{He}^+)}}{v_{n\,(\text{H})}} of the electron speeds in their respective nthn^{\text{th}} orbits. (b) Hence evaluate the ratio for n=2n=2. (c) State which electron moves faster in that orbit and give a physical explanation based on your result.

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