A chemist writes down the formulas NaCl, CaCl₂

CHEMISTRY · Multi-part · A Level · Chemistry · Bonding · Bonding

Problem

A chemist writes down the formulas NaCl, CaCl₂, and AlCl₃ while reviewing periodic trends. Using only the information contained in these formulas and your knowledge of atomic structure, analyze the series to reveal how elements that belong to different groups combine with chlorine. Answer all parts thoroughly and support each conclusion with explicit reasoning. (1) For each compound, state the charge on the cation that must be present to balance the chloride anions. (2) Write the complete systematic (Stock) name of each compound. (3) Describe in detail how the observed cation charges are related to (i) the group number of each element on the periodic table and (ii) the number of valence electrons those elements possess. (4) Gallium is located directly beneath aluminum in the periodic table. Predict the empirical formula and the systematic name of the binary chloride that gallium would form, and justify your prediction with reference to the trend established in parts (a)–(c).

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