Consider a galvanic cell constructed from the following two standard half-reactions

CHEMISTRY · Subjective · AP · Chemistry · Thermodynamics and Electrochemistry · Thermodynamics and Electrochemistry

Problem

Consider a galvanic cell constructed from the following two standard half-reactions. Cl2(g)+2 e−→2 Cl−(aq)\mathrm{Cl_2(g) + 2\,e^- \rightarrow 2\,Cl^-(aq)} E∘=+1.36 VE^\circ = +1.36\,\mathrm{V} I2(s)+2 e−→2 I−(aq)\mathrm{I_2(s) + 2\,e^- \rightarrow 2\,I^-(aq)} E∘=+0.54 VE^\circ = +0.54\,\mathrm{V} Calculate ΔG∘\Delta G^\circ (in kJ\mathrm{kJ}) for the spontaneous cell reaction at 298 K298\,\mathrm{K}. Use F=9.65×104 C mol−1F = 9.65 \times 10^4\,\mathrm{C\,mol^{-1}}.

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