Experimental data show that the two O–O bonds in O₃ are identical in length and strength

CHEMISTRY · Single correct · AP · Chemistry · Compound Structure and Properties · Compound Structure and Properties

Problem

Experimental data show that the two O–O bonds in O₃ are identical in length and strength. Which statement best justifies depicting O₃ with resonance structures? (a) Because the molecule rapidly oscillates between a single-bonded and a double-bonded form, the two bonds are observed to have the same length. (b) Equivalent bond lengths indicate that the π electrons are delocalized over both O–O bonds. (c) Equal bond lengths show that the σ electrons are shared equally between both O–O bonds. (d) Resonance structures are needed since no single drawing allows every oxygen atom to satisfy the octet rule without exceeding it.

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