Selected second-ionization-energy ( ) values are shown for two adjacent Period 3 elements

CHEMISTRY · Multi-part · A Level · Chemistry · Atomic structure · Atomic structure

Problem

Selected second-ionization-energy (I2I_2) values are shown for two adjacent Period 3 elements.
ElementI2I_2 (kJ mol−1^{-1})
Na4560
Mg1450
(1) Write the full electron configurations of (i) Na+^{+} and (ii) Mg+^{+} prior to removal of the second electron. (2) Using your configurations, explain in detail why I2I_2 for Na is substantially larger than I2I_2 for Mg. (3) Predict whether the difference between I2I_2 values for Al and Si will be greater than, less than, or approximately equal to the difference observed between Na and Mg. Support your prediction with atomic-level reasoning.

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