The chlorination of methane follows the steps (1) Cl₂ ⇌ 2 Cl (fast

CHEMISTRY · Subjective · AP · Chemistry · Kinetics · Kinetics

Problem

The chlorination of methane follows the steps (1) Cl₂ ⇌ 2 Cl (fast, reversible) (2) Cl + CH₄ → HCl + CH₃ (slow) (3) CH₃ + Cl₂ → CH₃Cl + Cl (fast) If the initial concentration of Cl₂ is tripled while [CH₄] remains constant, predict qualitatively how the initial rate will change (increase, decrease, or stay the same) and briefly justify your answer.

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