A galvanic cell is assembled at 298 K using the following half-reactions

CHEMISTRY · Single correct · AP · Chemistry · Thermodynamics and Electrochemistry · Thermodynamics and Electrochemistry

Problem

A galvanic cell is assembled at 298 K using the following half-reactions. Cu²⁺ + 2 e⁻ → Cu(s)  E° = +0.34 V Zn²⁺ + 2 e⁻ → Zn(s)  E° = –0.76 V The measured cell potential is 1.05 V when [Cu²⁺] = 1.0 M. Which statement about the concentration of Zn²⁺ in the Zn²⁺/Zn half-cell is most consistent with this measurement? (a) [Zn2+][\text{Zn}^{2+}] is less than 1.0 M1.0\,\text{M}.},{ (b) [Zn2+][\text{Zn}^{2+}] is greater than 1.0 M1.0\,\text{M}.},{ (c) Changing [Zn2+][\text{Zn}^{2+}] cannot influence the cell potential. (d) [Zn2+][\text{Zn}^{2+}] is exactly 1.0 M1.0\,\text{M}.}],

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