An object of mass m and specific heat capacity c cools from an initial temperature T1 to a final temperature T2(T1>T2) by coming into thermal contact with a very large heat reservoir that remains at the constant temperature T2. Assume c is constant in this temperature range and no work is done.
(i) Derive an expression for the entropy change of the object during its cooling.
(ii) Derive an expression for the entropy change of the reservoir.
(iii) Hence obtain the expression for the total entropy change of the universe in terms of m, c, T1, and T2.
(iv) Using m=0.50kg and c=450Jkg−1K−1, compute the total entropy change of the universe for the two separate cases:
(A) T1=350K to T2=300K
(B) T1=400K to T2=300K
Comment on how the initial temperature difference affects entropy generation.