At 1000 K, the pressure equilibrium constant for the decomposition is . A sealed…

CHEMISTRY · Subjective · A Level · Chemistry · Chemical equilibria (Le Chatelier’s principle and Kc) · Chemical equilibria (Le Chatelier’s principle and Kc)

Problem

At 1000 K, the pressure equilibrium constant for the decomposition CaCO3(s)⇋CaO(s)+CO2(g)\mathrm{CaCO_3(s) \leftrightharpoons CaO(s)+CO_2(g)} is Kp=0.11K_p = 0.11. A sealed vessel at this temperature contains CaCO3(s)\mathrm{CaCO_3(s)}, CaO(s)\mathrm{CaO(s)}, and CO2\mathrm{CO_2} at a partial pressure of 0.25 atm0.25\,\text{atm}. Compute QpQ_p, compare it with KpK_p, and predict whether additional CaCO3\mathrm{CaCO_3} will decompose or CaO\mathrm{CaO} and CO2\mathrm{CO_2} will recombine as the system approaches equilibrium.

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