A vessel of 2.50 litre was filled with 0.01 mole of and 0.01 mole of to attain the…

CHEMISTRY · Subjective · A Level · Chemistry · Chemical equilibria (Le Chatelier’s principle and Kc) · Chemical equilibria (Le Chatelier’s principle and Kc)

Problem

A vessel of 2.50 litre was filled with 0.01 mole of Sb2S3\text{Sb}_2\text{S}_3 and 0.01 mole of H2\text{H}_2 to attain the equilibrium at 440∘C440^\circ\text{C} as : Sb2S3(s)+3H2(g)⇌2Sb(s)+3H2S(g)\text{Sb}_2\text{S}_3(\text{s}) + 3\text{H}_2(\text{g}) \rightleftharpoons 2\text{Sb}(\text{s}) + 3\text{H}_2\text{S}(\text{g}) After equilibrium the H2S\text{H}_2\text{S} formed was analysed by dissolving it in water and treating with excess of Pb2+\text{Pb}^{2+} to give 1.029 g of PbS\text{PbS} as precipitate. What is value of KCK_C of the reaction at 440∘C440^\circ\text{C} ? (Atomic mass of Pb=206\text{Pb} = 206 )

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