The ferrous ion in a given sample is detected by the formation of a white precipitate on the addition of a potassium ferrocyanide solution to it. The precipitate has the constitutional formula.
(1) K2FeII[FeII(CN)6]
(2) K2FeIII[Fe(CN)6]
(3) KFeIII[FeII(CN)6]
(4) KFeII[FeIII(CN)6]