A aliquot of a solution containing and ions was acidified and titrated against…

CHEMISTRY · Subjective · A Level · Chemistry · Acids and bases · Acids and bases

Problem

A 25.0 cm325.0\,\text{cm}^3 aliquot of a solution containing Fe2+\text{Fe}^{2+} and Fe3+\text{Fe}^{3+} ions was acidified and titrated against 0.0200 mol dm−30.0200\,\text{mol dm}^{-3} potassium manganate(VII) solution, requiring 15.0 cm315.0\,\text{cm}^3. The solution was then reduced by zinc and, after filtering off the excess zinc, was titrated with the same potassium manganate(VII) solution, requiring 19.0 cm319.0\,\text{cm}^3. Calculate the concentrations of Fe2+\text{Fe}^{2+} and Fe3+\text{Fe}^{3+} in the solution.

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