Consider the reaction mechanism below

CHEMISTRY · Single correct · AP · Chemistry · Kinetics · Kinetics

Problem

Consider the reaction mechanism below. Step 1 2 NO2(g) + F2(g) → 2 NO2F(g) (slow) Step 2 NO2F(g) + NO2(g) → N2O4(g) + F2(g) (fast) Suppose the initial concentrations are [NO2]₀ and [F2]₀. If [NO2] is tripled and [F2] is simultaneously reduced to one-third of its original value, by what factor will the initial rate change? (a) It will increase by a factor of 99. (b) It will increase by a factor of 33. (c) It will decrease to one–third of its original value. (d) It will remain unchanged.

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