Let a=⟨3,−2,1⟩ and b=⟨k,4,−2⟩, where k is a real number.
(i) Calculate a⋅b when k=1.
(ii) Find the value of k for which a and b are perpendicular.
(iii) For the value of k obtained in part (ii), determine the angle between a and b+a, giving your answer in degrees to the nearest whole number.