Four pure liquids have the following normal boiling points: methanol 65 °C

CHEMISTRY · Single correct · A Level · Chemistry · Alkanes · Alkanes

Problem

Four pure liquids have the following normal boiling points: methanol 65 °C, butanone 80 °C, octane 126 °C, propanoic acid 141 °C. A fractional distillation is performed at 1 atm1\,\text{atm} on an equimolar mixture of all four liquids. Which component is expected to appear as the second major fraction collected (after the first fraction has largely ceased)? (a) Propanoic acid (141 ∘C^\circ\text{C}) (b) Methanol (65 ∘C^\circ\text{C}) (c) Butanone (80 ∘C^\circ\text{C}) (d) Octane (126 ∘C^\circ\text{C})

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