Which one is correct group reagent for group cations?

CHEMISTRY · Single correct · GCSE · Chemistry · Chemical Analysis · Chemical Analysis

Problem

Which one is correct group reagent for group cations? (1) Mn2+\text{Mn}^{2+} Co2+\text{Co}^{2+} Zn2+\text{Zn}^{2+} Ni2+\text{Ni}^{2+} ; HCl+H2S\text{HCl} + \text{H}_2\text{S} (2) Mn2+\text{Mn}^{2+} Co2+\text{Co}^{2+} Zn2+\text{Zn}^{2+} Ni2+\text{Ni}^{2+} ; dil. HCl\text{HCl} (3) Mn2+\text{Mn}^{2+} Co2+\text{Co}^{2+} Zn2+\text{Zn}^{2+} Ni2+\text{Ni}^{2+} ; NH4Cl+NH4OH\text{NH}_4\text{Cl} + \text{NH}_4\text{OH} (4) Mn2+\text{Mn}^{2+} Co2+\text{Co}^{2+} Zn2+\text{Zn}^{2+} Ni2+\text{Ni}^{2+} ; NH4Cl+NH4OH+H2S\text{NH}_4\text{Cl} + \text{NH}_4\text{OH} + \text{H}_2\text{S}

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