Two elements, M and N

CHEMISTRY · Single correct · AP · Chemistry · Atomic Structure and Properties · Atomic Structure and Properties

Problem

Two elements, M and N, each show one prominent valence-electron peak in their PES spectra. • For element M, the valence peak accounts for 1 electron and appears at 0.50 MJ mol⁻¹. • For element N, the valence peak accounts for 5 electrons and appears at 1.0 MJ mol⁻¹. Which of the following statements about their likely chemical behavior is most consistent with these data? (a) M readily gains one electron to form M−\mathrm{M}^-, whereas N tends to lose five electrons to form N5+\mathrm{N}^{5+}. (b) Both M and N form +1+1 ions because their valence electrons are readily removed at energies below 2 MJ mol−12\,\text{MJ\,mol}^{-1}. (c) M readily gains seven electrons to form M7−\mathrm{M}^{7-}, whereas N tends to gain three electrons to form N3−\mathrm{N}^{3-}. (d) M readily loses one electron to form M+\mathrm{M}^+, whereas N tends to gain three electrons to form N3−\mathrm{N}^{3-}.

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