Element M burns in excess oxygen to yield a solid whose empirical formula is When…

CHEMISTRY · Multi-part · CBSE · Chemistry · Redox Reactions · Redox Reactions

Problem

Element M burns in excess oxygen to yield a solid whose empirical formula is M2O2.\text{M}_{2}\text{O}_{2}. When this solid is carefully acidified with dilute sulfuric acid, O2\text{O}_{2} gas is evolved. Assume that the oxygen atoms in the solid have identical oxidation states. (a) Determine the oxidation state of oxygen in M2O2\text{M}_{2}\text{O}_{2} and explain how the laboratory observation supports your answer. (b) Deduce the ionic charge on element M in this compound. (c) Predict the empirical formula of the simplest chloride that element M would form and justify your prediction through charge balance. (d) The solid product is sometimes described as a "peroxide." Explain what distinguishes a peroxide ion from an oxide ion, both in terms of electron count and typical reactivity.

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