When an aqueous solution of copper (II) sulphate is saturated with ammonia, the blue compound crystallises on evaporation. The formula of this blue compound is :
(1) [Cu(NH3)4]SO4⋅H2O (square planar)
(2) [Cu(NH3)4]SO4 (Tetrahedral)
(3) [Cu(NH3)6]SO4 (Octahedral)
(4) [Cu(SO4)(NH3)5] (Octahedral)