Consider the two-step mechanism below

CHEMISTRY · Subjective · CBSE · Chemistry · Chemical Kinetics · Chemical Kinetics

Problem

Consider the two-step mechanism below, where all energy values are per mole: Step 1: A →\rightarrow B, Ea1,fwd=60 kJE_{a1,\text{fwd}} = 60\,\text{kJ}, ΔH1=+15 kJ\Delta H_1 = +15\,\text{kJ} Step 2: B →\rightarrow C, Ea2,fwd=95 kJE_{a2,\text{fwd}} = 95\,\text{kJ}, ΔH2=−40 kJ\Delta H_2 = -40\,\text{kJ} Provide the activation energies for the reverse directions of Step 1 and Step 2, respectively, in kJ\text{kJ}.

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