A student observes that the tangent to a reactant’s concentration–versus–time curve…

CHEMISTRY · Single correct · CBSE · Chemistry · Chemical Kinetics · Chemical Kinetics

Problem

A student observes that the tangent to a reactant’s concentration–versus–time curve at t=120 st=120\,\text{s} is noticeably less steep than the tangent at t=20 st=20\,\text{s}. Which statement most strongly accounts for this observation? (a) Temperature gradually decreases during the run, so molecular speed and collision frequency are lower at 120 s120\,\text{s} (b) Catalyst particles become consumed over the course of the reaction, so catalytic activity is essentially lost by 120 s120\,\text{s} (c) Reactant concentration is lower at 120 s120\,\text{s}, so fewer effective collisions occur each second (d) As product builds up, the reverse reaction increasingly competes with the forward reaction, reducing the net rate at 120 s120\,\text{s}

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