Which of the following best distinguishes a bond from a bond?
CHEMISTRY · Single correct · CBSE · Chemistry · Chemical Bonding and Molecular Structure · Chemical Bonding and Molecular Structure
Problem
Which of the following best distinguishes a σ bond from a π bond?
(a) A σ bond prevents rotation about the bond axis, whereas a π bond allows free rotation.
(b) A σ bond results from side-by-side overlap above and below the internuclear axis, whereas a π bond results from end-to-end overlap along that axis.
(c) A σ bond results from end-to-end overlap of orbitals along the internuclear axis, whereas a π bond results from side-by-side overlap above and below that axis.
(d) A σ bond is weaker than a π bond because its orbital overlap is less extensive.