Which of the following best distinguishes a bond from a bond?

CHEMISTRY · Single correct · CBSE · Chemistry · Chemical Bonding and Molecular Structure · Chemical Bonding and Molecular Structure

Problem

Which of the following best distinguishes a σ\sigma bond from a π\pi bond? (a) A σ\sigma bond prevents rotation about the bond axis, whereas a π\pi bond allows free rotation. (b) A σ\sigma bond results from side-by-side overlap above and below the internuclear axis, whereas a π\pi bond results from end-to-end overlap along that axis. (c) A σ\sigma bond results from end-to-end overlap of orbitals along the internuclear axis, whereas a π\pi bond results from side-by-side overlap above and below that axis. (d) A σ\sigma bond is weaker than a π\pi bond because its orbital overlap is less extensive.

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