A particulate diagram for the equilibrium 2NO₂(g) ⇌ N₂O₄(g) shows 3 NO₂ molecules and…

CHEMISTRY · Single correct · CBSE · Chemistry · Equilibrium · Equilibrium

Problem

A particulate diagram for the equilibrium 2NO₂(g) ⇌ N₂O₄(g) shows 3 NO₂ molecules and 2 N₂O₄ molecules in identical containers of equal volume and temperature. Which statement best describes the magnitude of the equilibrium constant, Kc, for this reaction under these conditions? (a) KcK_c equals 11 because the forward and reverse reaction rates are equal at equilibrium. (b) KcK_c is less than 11 because the denominator of the equilibrium expression is larger than the numerator. (c) KcK_c is greater than 11 because the equilibrium expression is written as [NO2]2/[N2O4][NO_2]^2/[N_2O_4], which gives a value larger than 11 when the particle numbers are substituted. (d) KcK_c cannot be inferred from the diagram because the actual concentrations are not given.

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