For the elementary gas-phase reaction

CHEMISTRY · Single correct · AP · Chemistry · Kinetics · Kinetics

Problem

For the elementary gas-phase reaction 2 X(g)+Y(g)→Z(g)2\,\mathrm{X}(g)+\mathrm{Y}(g)\rightarrow\mathrm{Z}(g), concentrations are measured in mol L−1\text{mol L}^{-1} and time in s\text{s}. Which combination of rate law and corresponding units for kk is correct? (a) rate =k[X]2[Y]2=k[\mathrm{X}]^{2}[\mathrm{Y}]^{2}; kk in L3 mol−3 s−1\text{L}^{3}\,\text{mol}^{-3}\,\text{s}^{-1} (b) rate =k[X]2[Y]=k[\mathrm{X}]^{2}[\mathrm{Y}]; kk in L  mol−1 s−1\text{L\;mol}^{-1}\,\text{s}^{-1} (c) rate =k[X]2[Y]=k[\mathrm{X}]^{2}[\mathrm{Y}]; kk in L2 mol−2 s−1\text{L}^{2}\,\text{mol}^{-2}\,\text{s}^{-1} (d) rate =k[X][Y]=k[\mathrm{X}][\mathrm{Y}]; kk in L  mol−1 s−1\text{L\;mol}^{-1}\,\text{s}^{-1}

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