A fixed-volume container initially shows 5 ions and 10 ions dispersed among many…

CHEMISTRY · Single correct · AP · Chemistry · Properties of Substances and Mixtures · Properties of Substances and Mixtures

Problem

A fixed-volume container initially shows 5 Ca2+Ca^{2+} ions and 10 Cl−Cl^{-} ions dispersed among many water molecules. The solution is left to evaporate until the volume of water is reduced by half; no solute precipitates. Which change best describes how the particle diagram should be redrawn? (a) The numbers of Ca2+Ca^{2+} and Cl−Cl^{-} ions double, while the number of water molecules stays the same. (b) Both the numbers of Ca2+Ca^{2+} and Cl−Cl^{-} ions are halved, along with the water molecules, since some ions evaporate with the solvent. (c) The numbers of Ca2+Ca^{2+} and Cl−Cl^{-} ions remain 5 and 10, respectively, but the ions appear twice as densely packed among fewer water molecules. (d) The number of Cl−Cl^{-} ions remains 10 while Ca2+Ca^{2+} ions decrease to 3, altering the Ca2+:Cl−Ca^{2+}:Cl^{-} ratio.

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