A chemist investigates the following half–reaction that occurs under acidic conditions

CHEMISTRY · Multi-part · A Level · Chemistry · Oxidation, reduction and redox reactions · Oxidation, reduction and redox reactions

Problem

A chemist investigates the following half–reaction that occurs under acidic conditions. NO3−(aq)+2H+(aq)+e−→NO2(g)+H2O(l)\text{NO}_3^{-}(aq) + 2 \text{H}^{+}(aq) + e^{-} \rightarrow \text{NO}_2(g) + \text{H}_2\text{O}(l) Carefully study the half-reaction and respond to the prompts. (1) Classify the half-reaction as an oxidation process or a reduction process. (2) Justify your classification by referring explicitly to electron transfer and to changes in oxidation number for nitrogen. (3) Based solely on the half-reaction above, indicate whether NO3−\text{NO}_3^{-} or NO2\text{NO}_2 would act as the oxidizing agent in an overall redox reaction, and explain your reasoning.

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