At and . For the cell . Calculate entropy and enthalpy change in this standard…

CHEMISTRY · Single correct · A Level · Chemistry · Electrode potentials · Electrode potentials

Problem

At 27∘C27^\circ\text{C} (dE∘dT)P=−1.45×10−3 V K−1\left(\frac{dE^\circ}{dT}\right)_P = -1.45 \times 10^{-3}\,\text{V K}^{-1} and E∘=1.36 VE^\circ = 1.36\,\text{V}. For the cell Pt∣H2(g)∣HCl(aq)∣Cl2∣Pt\text{Pt} | \text{H}_2(\text{g}) | \text{HCl}(\text{aq}) | \text{Cl}_2 | \text{Pt}. Calculate entropy and enthalpy change in this standard state. (a) −962.48 J K−1-962.48\,\text{J K}^{-1}, −346.435 kJ-346.435\,\text{kJ} (b) −279.85 J K−1-279.85\,\text{J K}^{-1}, −346.435 kJ-346.435\,\text{kJ} (c) −1326.23 J K−1-1326.23\,\text{J K}^{-1}, −346.435 kJ-346.435\,\text{kJ} (d) −280.24 J K−1-280.24\,\text{J K}^{-1}, −346.435 kJ-346.435\,\text{kJ}

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