For the reaction the observed rate law is

CHEMISTRY · Single correct · AP · Chemistry · Kinetics · Kinetics

Problem

For the reaction C+D→productsC + D \to \text{products} the observed rate law is rate=k [C]2\text{rate} = k\,[C]^2. Three mechanisms are proposed. I. Step 1 (slow): C+C→intermediate→productsC + C \to \text{intermediate} \to \text{products} II. Step 1 (slow): C+D→intermediateC + D \to \text{intermediate} Step 2 (fast): intermediate+C→products\text{intermediate} + C \to \text{products} IV. Single elementary step: 2 C→products2\,C \to \text{products} (slow) Based on the rate law, which mechanism is impossible? (a) Mechanism I (b) Mechanism IV (c) Mechanism II

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