A reaction between substances X and Y shows the following kinetic behavior at 298 K:…

CHEMISTRY · Subjective · AP · Chemistry · Kinetics · Kinetics

Problem

A reaction between substances X and Y shows the following kinetic behavior at 298 K: • Doubling [X] while holding [Y] constant doubles the initial rate. • Doubling [Y] while holding [X] constant increases the initial rate by a factor between 3.6 and 4.0. Three mechanisms have been proposed (overall reaction X + 2 Y → products): Mechanism 1 Step 1 (slow): X + Y → Z Mechanism 2 Step 1 (slow): Y + Y → W Mechanism 3 Step 1 (slow): X + 2 Y → products Which mechanism (1, 2, or 3) cannot be ruled out by the experimental rate data?

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