An emission spectrum of a gas shows a set of bright, well-defined lines rather than a continuous band. Which of the following explanations is most consistent with this observation?
(a) Electronsinthegasemitonlythosewavelengthsthatcanresonatewiththemeanfreepathoftheatoms,producingdiscretelines.
(b) ThebrightlinesresultfromDopplershiftsthatseparateacontinuousspectrumintodistinctwavelengthsasatomsmoveatdifferentspeeds.
(c) Electronsinthegascanoccupyonlycertainquantizedenergystates,sophotonsareemittedonlywithenergiesequaltodifferencesbetweenthosestates.
(d) Onlyafewwavelengthsareabletoescapethegaswithoutbeingre-absorbed,givingtheillusionofanemissionlinespectrum.