A teacher sketches a particulate-level diagram for an aqueous solution of MgCl₂

CHEMISTRY · Single correct · AP · Chemistry · Properties of Substances and Mixtures · Properties of Substances and Mixtures

Problem

A teacher sketches a particulate-level diagram for an aqueous solution of MgCl₂. In the fixed-volume box, six particles are labeled “Mg⁺,” each surrounded by several water molecules with the H atoms pointed toward the ion. Twelve particles labeled “Cl⁻” are dispersed throughout the box, each with the O atom of nearby water molecules pointed toward the ion. Which statement identifies the MOST significant error in the diagram? (a) Water molecules are oriented incorrectly around the magnesium ions; the oxygen atoms, not the hydrogen atoms, should face the cations. (b) The ratio of chloride ions to magnesium ions is incorrect; the diagram should show an equal number of each ion. (c) The diagram should depict chloride ions paired with magnesium ions as intact MgCl2\text{MgCl}_2 formula units rather than separated ions. (d) Magnesium ions are shown with a +1 charge even though each Mg ion in solution carries a +2 charge.

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