A reaction proceeds by the mechanism shown below

CHEMISTRY · Single correct · A Level · Chemistry · Rate equations · Rate equations

Problem

A reaction proceeds by the mechanism shown below. Steps 1 and 2 are rapid and reversible; Step 3 is slow. Step 1 A + B ⇌ C K₁ = 4.0 Step 2 C ⇌ D + B K₂ = 0.50 Step 3 D → products kₛ = 1.2 × 10⁻³ s⁻¹ Initially [A] = 0.20 M and [B] = 0.10 M. Which value is closest to the initial rate of product formation? (a) 4.8×10−4  M s−14.8\times 10^{-4}\;\text{M\,s}^{-1} (b) 1.0×10−4  M s−11.0\times 10^{-4}\;\text{M\,s}^{-1} (c) 2.4×10−4  M s−12.4\times 10^{-4}\;\text{M\,s}^{-1} (d) 9.6×10−4  M s−19.6\times 10^{-4}\;\text{M\,s}^{-1}

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