Three different acetate buffer concentrates are prepared at

CHEMISTRY · Single correct · A Level · Chemistry · Acids and bases · Acids and bases

Problem

Three different acetate buffer concentrates are prepared at 25∘C25^{\circ}\text{C}. A. 100 mL100\,\text{mL} of 0.50 M0.50\,\text{M} CH3COOH\text{CH}_3\text{COOH} and 0.50 M0.50\,\text{M} CH3COO−\text{CH}_3\text{COO}^- B. 50 mL50\,\text{mL} of 1.00 M1.00\,\text{M} CH3COOH\text{CH}_3\text{COOH} and 0.20 M0.20\,\text{M} CH3COO−\text{CH}_3\text{COO}^- C. 200 mL200\,\text{mL} of 0.20 M0.20\,\text{M} CH3COOH\text{CH}_3\text{COOH} and 0.80 M0.80\,\text{M} CH3COO−\text{CH}_3\text{COO}^- Each concentrate is separately diluted with water to a final volume of 1.00 L1.00\,\text{L}, then titrated with NaOH (aq)\text{NaOH}\,(aq). Which order correctly ranks the resulting buffers from greatest to least capacity to neutralize the added base? (a) B>C>AB > C > A (b) C>A>BC > A > B (c) A>B>CA > B > C (d) C>B>AC > B > A

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