Assertion : The blue precipitate formed by the action of K4[Fe(CN)6] on Fe3+ and by…

CHEMISTRY · Subjective · ISC · Chemistry · Coordination Compounds · Coordination Compounds

Problem

Assertion : The blue precipitate formed by the action of K4[Fe(CN)6] on Fe3+ and by that of K3[Fe(CN)6] on Fe2+ have the same composition. Reason : [Fe(CN)6]3- oxidises Fe2+ to Fe3+ and itself gets reduced to [Fe(CN)6]4-.

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