Three phosphate buffers are listed below

CHEMISTRY · Subjective · CBSE · Chemistry · Equilibrium · Equilibrium

Problem

Three phosphate buffers are listed below, each at 1.0 L1.0\,\text{L} total volume. (a) 0.30 mol H2PO4−0.30\,\text{mol}\ \mathrm{H_2PO_4^-} and 0.70 mol HPO42−0.70\,\text{mol}\ \mathrm{HPO_4^{2-}} (b) 0.50 mol H2PO4−0.50\,\text{mol}\ \mathrm{H_2PO_4^-} and 0.50 mol HPO42−0.50\,\text{mol}\ \mathrm{HPO_4^{2-}} (c) 0.40 mol HPO42−0.40\,\text{mol}\ \mathrm{HPO_4^{2-}} and 0.60 mol PO43−0.60\,\text{mol}\ \mathrm{PO_4^{3-}} A process will introduce 0.050 mol0.050\,\text{mol} of HCl\mathrm{HCl} into the solution. Identify which buffer will best resist the resulting pH decrease. Write the net ionic equation that shows how that buffer neutralizes the added HCl\mathrm{HCl}.

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