CaO has a substantially larger lattice energy than KF

CHEMISTRY · Single correct · A Level · Chemistry · Bonding · Bonding

Problem

CaO has a substantially larger lattice energy than KF. Which statement best accounts for this difference? (a) The K+^{+} ion is smaller than the Ca2+^{2+} ion, leading to stronger attractions and therefore a higher lattice energy in KF. (b) KF has a more closely packed crystal structure than CaO, which reduces the distance between ions and gives KF the greater lattice energy. (c) Both ions in CaO carry charges of ±2\pm 2, whereas the ions in KF carry charges of only ±1\pm 1. (d) The greater electronegativity difference between K and F makes the bonds in KF more ionic, so its lattice energy is larger than that of CaO.

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