Which of the following best explains why SO₂ possesses a permanent dipole moment…

CHEMISTRY · Single correct · A Level · Chemistry · Bonding · Bonding

Problem

Which of the following best explains why SO₂ possesses a permanent dipole moment whereas CO₂ does not? (a) Sulfur is more electronegative than oxygen, making SO2\mathrm{SO_2} polar, whereas carbon is less electronegative than oxygen in CO2\mathrm{CO_2}. (b) A lone pair of electrons on the sulfur atom in SO2\mathrm{SO_2} creates an uneven charge distribution, while the central carbon atom in CO2\mathrm{CO_2} has no lone pair. (c) SO2\mathrm{SO_2} has a bent geometry that prevents cancellation of its S–O bond dipoles, whereas CO2\mathrm{CO_2} is linear so its bond dipoles cancel. (d) Because SO2\mathrm{SO_2} has resonance structures with unequally distributed charges, but the resonance forms of CO2\mathrm{CO_2} are completely symmetric.

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