An industrial synthesis step involves an elementary reaction with an activation…

CHEMISTRY · Multi-part · A Level · Chemistry · Kinetics · Kinetics

Problem

An industrial synthesis step involves an elementary reaction with an activation energy of 92 kJ·mol⁻¹. The process is currently operated at 300 K. (a) By how many kelvin must the temperature be increased to double the rate constant, assuming the pre-exponential factor remains constant? Express your answer to the nearest kelvin. (b) Alternatively, the company could introduce a catalyst at 300 K. By how many kJ·mol⁻¹ must the activation energy be lowered to achieve the same doubling of the rate constant? (c) Compare the relative magnitudes of the temperature increase and the activation-energy decrease you calculated in parts (a) and (b). Based on your results and practical industrial considerations, discuss which strategy is likely to be more feasible.

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