The termolecular reaction 2 ,NO(g) + Cl_ 2 (g) 2 ,NOCl(g) proceeds according to the…

CHEMISTRY · Single correct · A Level · Chemistry · Rate equations · Rate equations

Problem

The termolecular reaction 2 NO(g)+Cl2(g)→2 NOCl(g)\mathrm{2\,NO(g) + Cl_{2}(g) \rightarrow 2\,NOCl(g)} proceeds according to the mechanism whose first elementary step is rate-determining: 2 NO+Cl2→2 NOCl    (slow)\mathrm{2\,NO + Cl_{2} \rightarrow 2\,NOCl} \;\; (\text{slow}) If the concentration of NO is tripled while the concentration of Cl2\mathrm{Cl_{2}} remains unchanged, by what factor is the initial rate expected to change? (a) 33 (b) 2727 (c) 99 (d) 66

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