The nitrite ion,

CHEMISTRY · Multi-part · A Level · Chemistry · Bonding · Bonding

Problem

The nitrite ion, NO2−\mathrm{NO_2^-}, plays a significant role in environmental chemistry and biological nitrogen cycles. (a) Draw every valid resonance structure for NO2−\mathrm{NO_2^-} that obeys the octet rule. Include all lone pairs and show formal charges. (b) Using the resonance structures from part (a), determine the average N–O bond order in NO2−\mathrm{NO_2^-}. Clearly show the steps in your calculation. (c) Based on your bond-order result from part (b), predict whether the two N–O bond lengths in NO2−\mathrm{NO_2^-} are expected to be equal or different. Justify your prediction.

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