A white solid A reacts with dilute to produce a colourless gas B and a colourless…

CHEMISTRY · Single correct · ICSE · Chemistry · Analytical Chemistry · Analytical Chemistry

Problem

A white solid A reacts with dilute H2SO4\text{H}_2\text{SO}_4 to produce a colourless gas B and a colourless solution C. The reaction between B and acidified dichromate yields a green solution and a slightly coloured precipitate D. The substance D, when burnt in air, gives a gas E which reacts with B to yield D and a colourless liquid. Anhydrous copper sulphate turns blue with this colourless liquid. The addition of aqueous NH3\text{NH}_3 or NaOH\text{NaOH} to C produces a precipitate that dissolves in an excess of the reagent to form a clear solution. What would appear if the gas B were passed through an aqueous solution of Pb(NO3)2\text{Pb}(\text{NO}_3)_2 ? (1) A white precipitate soluble in hot dilute HNO3\text{HNO}_3 (2) A black precipitate soluble in hot dilute HNO3\text{HNO}_3 (3) A black precipitate insoluble in hot dilute HNO3\text{HNO}_3 (4) A yellow precipitate soluble in hot concentrated HNO3\text{HNO}_3

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