Dinitrogen pentoxide decomposes in the gas phase according to the elementary process…

CHEMISTRY · Multi-part · A Level · Chemistry · Rate equations · Rate equations

Problem

Dinitrogen pentoxide decomposes in the gas phase according to the elementary process N₂O₅(g) → 2 NO₂(g) + 1⁄2 O₂(g) When the experiment is performed at 308 K, the reaction is first order in N₂O₅. Initial-rate data are provided.
Trial[N₂O₅]₀ (M)Initial rate (mol·L⁻¹·s⁻¹)
10.0501.2 × 10⁻⁴
20.1002.5 × 10⁻⁴
(a) Write the complete rate law for the decomposition reaction, including the rate constant. (b) Calculate the value of k for each trial. Show your work and include correct units. (c) Average the two trial values to obtain a single reported k. State the final value with appropriate significant figures and units.

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