A student prepares a solution containing equimolar amounts of ammonium chloride ( )…

CHEMISTRY · Single correct · A Level · Chemistry · Acids and bases · Acids and bases

Problem

A student prepares a solution containing equimolar amounts of ammonium chloride (NH4ClNH_4Cl) and sodium acetate (NaCH3COONaCH_3COO). Two separate proton-transfer equilibria occur: 1. NH4++H2O⇌NH3+H3O+NH_4^+ + H_2O \rightleftharpoons NH_3 + H_3O^+ 2. CH3COO−+H2O⇌CH3COOH+OH−CH_3COO^- + H_2O \rightleftharpoons CH_3COOH + OH^- Which pair correctly describes the role of water in each equilibrium? (a) Equilibrium 1: water is the acid; Equilibrium 2: water is the base. (b) Equilibrium 1: water is the base; Equilibrium 2: water is the base. (c) Equilibrium 1: water is the base; Equilibrium 2: water is the acid. (d) Equilibrium 1: water is both acid and base; Equilibrium 2: water is both acid and base.

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