A sample of and was dissolved in dil

CHEMISTRY · Subjective · CBSE · Chemistry · Redox Reactions · Redox Reactions

Problem

A sample of Fe2(SO4)3\text{Fe}_2(\text{SO}_4)_3 and FeC2O4\text{FeC}_2\text{O}_4 was dissolved in dil. H2SO4\text{H}_2\text{SO}_4. The complete oxidation of reaction mixture required 40 mL of N/16 KMnO4N/16\ \text{KMnO}_4. After the oxidation, the reaction mixture was reduced by Zn and dil. H2SO4\text{H}_2\text{SO}_4. H2SO4\text{H}_2\text{SO}_4. On again oxidation by same KMnO4\text{KMnO}_4, 60 mL were required. Calculate the ratio of Mecq. of Fe2(SO4)3\text{Fe}_2(\text{SO}_4)_3 and FeC2O4\text{FeC}_2\text{O}_4 in mixture.

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