For a reaction carried out at

CHEMISTRY · Single correct · AP · Chemistry · Equilibrium · Equilibrium

Problem

For a reaction carried out at 298 K298\,\text{K}, ΔG∘\Delta G^{\circ} is reported to be −35 kJ mol−1-35\,\text{kJ mol}^{-1}. Which statement about the equilibrium constant KK for this reaction is MOST accurate? (a) KK is much less than 1 because the negative value of ΔG∘\Delta G^{\circ} makes ln⁡K\ln K negative. (b) KK is approximately 1 since ΔG∘/(RT)≈0.01\Delta G^{\circ}/(RT)\approx 0.01 at 298 K298\,\text{K}. (c) KK is on the order of 10610^{6}; a large negative ΔG∘\Delta G^{\circ} means the equilibrium lies far toward products. (d) KK is roughly 101410^{14} because using log⁡\log instead of ln⁡\ln in the calculation gives a much larger value.

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