From the stability constant (hypothetical values)

CHEMISTRY · Single correct · CBSE · Chemistry · Coordination Compounds · Coordination Compounds

Problem

From the stability constant (hypothetical values), given below, predict which is the most stable complex ? (1) Cu2++4NH3⟶[Cu(NH3)4]2+Cu^{2+} + 4NH_3 \longrightarrow [Cu(NH_3)_4]^{2+}, K=4.5×1011K = 4.5 \times 10^{11} (2) Cu2++4CN−⟶[Cu(CN)4]2−Cu^{2+} + 4CN^- \longrightarrow [Cu(CN)_4]^{2-}, K=2.0×1027K = 2.0 \times 10^{27} (3) Cu2++2en⟶[Cu(en)2]2+Cu^{2+} + 2en \longrightarrow [Cu(en)_2]^{2+}, K=3.0×1015K = 3.0 \times 10^{15} (4) Cu2++4H2O⟶[Cu(H2O)4]2+Cu^{2+} + 4H_2O \longrightarrow [Cu(H_2O)_4]^{2+}, K=9.5×108K = 9.5 \times 10^8

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