The reaction has a standard cell potential at and involves electrons
CHEMISTRY · Subjective · AP · Chemistry · Thermodynamics and Electrochemistry · Thermodynamics and Electrochemistry
Problem
The reaction
2Cr3+(aq)+3Fe(s)⇌2Cr(s)+3Fe2+(aq)
has a standard cell potential E∘=+0.30V at 298K and involves n=6 electrons. Initial concentrations are [Cr3+]=0.20M and [Fe2+]=1.0×10−4M; all solids are in their standard states. Determine whether the system will spontaneously form more Cr(s) (proceed to the right) or oxidize Cr(s) (proceed to the left) as it moves toward equilibrium, and support your answer with a brief calculation.