The reaction has a standard cell potential at and involves electrons

CHEMISTRY · Subjective · AP · Chemistry · Thermodynamics and Electrochemistry · Thermodynamics and Electrochemistry

Problem

The reaction 2 Cr3+(aq)+3 Fe(s)⇌2 Cr(s)+3 Fe2+(aq)2\,\text{Cr}^{3+}(aq) + 3\,\text{Fe}(s) \rightleftharpoons 2\,\text{Cr}(s) + 3\,\text{Fe}^{2+}(aq) has a standard cell potential E∘=+0.30 VE^\circ = +0.30\,\text{V} at 298 K298\,\text{K} and involves n=6n = 6 electrons. Initial concentrations are [Cr3+]=0.20 M[\text{Cr}^{3+}] = 0.20\,\text{M} and [Fe2+]=1.0×10−4 M[\text{Fe}^{2+}] = 1.0 \times 10^{-4}\,\text{M}; all solids are in their standard states. Determine whether the system will spontaneously form more Cr(s)\text{Cr}(s) (proceed to the right) or oxidize Cr(s)\text{Cr}(s) (proceed to the left) as it moves toward equilibrium, and support your answer with a brief calculation.

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