An electron in a hydrogen atom can de-excite either from to or from to

CHEMISTRY · Single correct · A Level · Chemistry · Atomic structure · Atomic structure

Problem

An electron in a hydrogen atom can de-excite either from n=4n=4 to n=3n=3 or from n=4n=4 to n=2n=2. Which one of the following statements about the photons emitted in these two transitions is correct? (a) Both photons possess the same energy and therefore the same wavelength, since they start from the same initial level. (b) The n=4→3n=4\rightarrow3 photon has higher energy and a shorter wavelength than the n=4→2n=4\rightarrow2 photon. (c) The n=4→2n=4\rightarrow2 photon has higher energy and a shorter wavelength than the n=4→3n=4\rightarrow3 photon. (d) The n=4→3n=4\rightarrow3 photon has lower energy and a shorter wavelength than the n=4→2n=4\rightarrow2 photon.

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