A buffer in seawater is often modeled by the conjugate pair HPO /PO

CHEMISTRY · Multi-part · A Level · Chemistry · Acids and bases · Acids and bases

Problem

A buffer in seawater is often modeled by the conjugate pair HPO42−_4^{2-}/PO43−_4^{3-}. Consider 100.0 mL of a solution that is 0.20 M in each species. A researcher investigates how the buffer responds to two different additions. (a) When 5.0 mL of 1.0 M NaOH is added, write the balanced net ionic equation that describes the reaction occurring in the buffer. (b) When 5.0 mL of 1.0 M HCl is added to a fresh 100.0 mL sample of the same buffer, write the balanced net ionic equation that describes the reaction. (c) Compare the conjugate acid–base roles of HPO42−_4^{2-} and PO43−_4^{3-} in parts (a) and (b), citing evidence from the equations you wrote.

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